文献:功能性可生物降解聚己内酯的合成、表征及热性能
链接:https://www.atlantis-press.com/proceedings/icismme-15/21016
作者:高伟娜,熊艳照
节选:
介绍了一种制备功能基团聚己内酯 (PCL) 的新方法,设计并合成了三种功能基团封端的 PCL(PCL-OH、PCL-Boc 和 PCL-NH2)。采用傅立叶变换红外光谱 (FTIR)、核磁共振 (NMR) 和热重分析 (TGA) 表征了这些功能性 PCL 的组成、结构和热性能。结果表明,PCL-OH、PCL-Boc 和 PCL-NH2 已成功合成。该新型多功能合成平台可提供一系列可生物降解的功能基团封端共聚酯,可用于制备新型可生物降解聚酯弹性体。
Abstract
A new approach for preparing polycaprolactone (PCL) with functional groups was introduced, by which three kinds of functional group-terminated PCLs (PCL-OH, PCL-Boc and PCL-NH2) were designed and synthesized. The composition, structure, and thermal property of these functional PCLs were characterized by FTIR, NMR and TGA. The results show that PCL-OH, PCL-Boc and PCL-NH2 were synthesized successfully. This new versatile synthetic platform can provide a large family of biodegradable, functional group-terminated copolyesters which are useful for the preparation of novel biodegradable polyester elastomer.
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PEG-PLGA纳米胶束装载荧光染料
PEG-PLGA纳米胶束特殊定制(表面可修饰*体、多肽、小分子、适配体等)
PCL-OH
PCL-COOH
PCL-COOR
PCL-NH2
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