ILs不仅影响SACs的稳定性,还会影响催化性能。为了保证所有催化剂的稳定性,在室温下丙烯加氢的活性(图1A)。经过离子液体改性的0.2Pt1/HAP相对未改性的0.2Pt1/HAP,如图1B所示,BmimTf2N-0.2Pt1/HAP的表观活化能明显低于0.2Pt1/HAP,这也证明了离子液体改性后的SACs具有一个更好的催化活性。
图2通过DFT研究添加[Bmim][BF4]对HAP上负载的Pt单原子发生团聚的影响。
如图2所示,Pt单原子在HAP上并不稳定,两个单原子Pt形成Pt二聚体,仅需克服0.11 eV的能垒,而当添加[Bmim][BF4]时,BF4-会与Pt单原子桥接,阻碍其形成二聚体,使其形成二聚体的能垒提高了6倍。
DFT结果表明,阴离子通过与载体上的Pt直接相互作用,在稳定Pt单原子并调节其电子结构中起主导作用,而阳离子则平衡电荷,并可能提供额外的空间稳定性。
图3 ILs改性提高了一系列单原子Pt和Pd催化剂稳定性的相关表征。
为了证实ILs改性是稳定不同基底上单原子催化剂的普适方法,将[Bmim][Tf2N]分别涂覆在分散在CeO2、金红石TiO2、单斜ZrO2等多种载体上的单原子Pt物种上。如图3A所示,在H2中于200°C还原1小时后,所有离子液体改性的单原子催化剂仍然在2080 cm-1处显示了一个CO的主要吸收峰。而没有离子液体改性的单原子催化剂则在2053和2037 cm-1处出现了强峰,且在1800 cm-1出现宽峰,这都表明了CO吸附在了Pt纳米颗粒上。
此外,将Pd单原子负载在HAP上(0.02Pd1/HAP),并对其进行离子液体改性,得到样品[Bmim][BF4]-Pd1/HAP。在H2中于100°C还原后,未改性的0.02Pd1/HAP催化剂活性增加,但选择性**降低,表明Pd单原子经还原处理后烧结成了Pd NPs(图3D),而改性后的[Bmim][BF4]-Pd1/HAP催化剂的活性和稳定性均有提升,表明其仍保持原子分散(图3E)。图5B和5C的耐久性测试,也证明了改性后的催化剂表现出更好的稳定性。
产品供应列表:
1-HexylImidazoliumdiHydrogenPhosphate
[C6Im]TS
1-己基咪唑对甲苯磺酸盐
1-HexylImiazoliumTosylate
[C6Im]TfS
1-己基咪唑三氟甲磺酸盐
1-HexylImidazoliumtriFluoroMethaneSulfonate
[C6Im]NO3
1-己基咪唑硝酸盐
1-HexylImidazoliumNitrate
[C6Im]Ac
1-己基咪唑醋酸盐
1-HexylImidazoliumAcetate
[C6Im]TfAc
1-己基咪唑三氟乙酸盐
1-HexylImidazoliumtriFluoroAcetate
[C8Im]X
[C8Im]Cl
1-辛基咪唑氯盐
1-OctylImidazoliumChloride
[C8Im]BF4
1-辛基咪唑四氟硼酸盐
1-OctylImidazoliumtetraFluoroBorate
[C8Im]HSO4
1-辛基咪唑硫酸氢盐
1-OctylImidazoliumHydrogenSulfate
[C8Im]H2PO4
1-辛基咪唑磷酸二氢盐
1-OctylImidazoliumdiHydrogenPhosphate
[C8Im]M
1-辛基咪唑甲磺酸盐
1-OctylImidazoliumMethaneSulfonate
[C8Im]TS
1-辛基咪唑对甲苯磺酸盐
1-OctylImidazoliumTosylate
[C8m]TfS
1-辛基咪唑三氟甲磺酸盐
1-OctylImidazoliumtriFluoroMethaneSulfonate
[C8Im]NO3
1-辛基咪唑硝酸盐
1-OctylImidazoliumNitrate
[C8Im]Ac
1-辛基咪唑醋酸盐
1-OctylImidazoliumAcetate
[C8Im]TfAc
1-辛基咪唑三氟乙酸盐
1-OctylImidazoliumtriFluoroAcetate
[C10Im]X
[C10Im]Cl
1-癸基咪唑氯盐
1-DecylImidazoliumChloride
[C10Im]BF4
1-癸基咪唑四氟硼酸盐
1-DecylImidazoliumtetraFluoroBorate
[C10Im]HSO4
1-癸基咪唑硫酸氢盐
1-DecylImidazoliumHydrogenSulfate
[C10Im]H2PO4
1-癸基咪唑磷酸二氢盐
1-DecylImidazoliumdiHydrogenPhosphate
[C10Im]TS
1-癸基咪唑对甲苯磺酸盐
1-DecylImidazoliumTosylate
[C10m]TfS
1-癸基咪唑三氟甲磺酸盐
1-DecylImidazoliumtriFluoroMethaneSulfonate
[C10Im]NO3
1-癸基咪唑硝酸盐
1-DecylImidazoliumNitrate
[C10Im]Ac
1-癸基咪唑醋酸盐
1-DecylImidazoliumAcetate
[C10Im]TfAc
1-癸基咪唑三氟乙酸盐
1-DecylImidazoliumtriFluoroAcetate
[C12Im]X
[C12Im]Cl
1-十二烷基咪唑氯盐
1-DodecylImidazoliumChloride
[C12Im]BF4
1-十二烷基咪唑四氟硼酸盐
1-DodecylImidazoliumtetraFluoroBorate
[C12Im]HSO4
1-十二烷基咪唑硫酸氢盐
1-DodecylImidazoliumHydrogenSulfate
[C12Im]H2PO4
1-十二烷基咪唑磷酸二氢盐
1-DodecylImidazoliumdiHydrogenPhosphate
[C12Im]TS
1-十二烷基咪唑对甲苯磺酸盐
1-DodecylImidazoliumTosylate
[C12m]TfS
1-十二烷基咪唑三氟甲磺酸盐
1-DodecylImidazoliumtriFluoroMethaneSulfonat
[C12Im]NO3
1-十二烷基咪唑硝酸盐
1-DodecylImidazoliumNitrate
[C12Im]Ac
1-十二烷基咪唑醋酸盐
1-DodecylImidazoliumAcetate
[C12Im]TfAc
1-十二烷基咪唑三氟乙酸盐
1-DodecylImidazoliumtriFluoroAcetate
[S1Y2S3Im]X
N1,N3-双对称取代咪唑型
[(iC3)2Im]X
[(iC3)2Im]Cl
139143-09-2
1,3-二异丙基咪唑氯盐
[(iC3)2Im]BF4
286014-34-4
1,3-二异丙基咪唑四氟硼酸盐
[(CNC1)2Im]X
[M2XIm]X
[M2ClIm]Cl
37091-73-9
2-氯-1,3-二甲基咪唑氯盐
[M2ClIm]BF4
153433-26-2
2-氯-1,3-二甲基咪唑四氟硼酸盐
[M2ClIm]PF6
101385-69-7
2-氯-1,3-二甲基咪唑六氟磷酸盐
[M2FIm]PF6
164298-27-5
2-氟-1,3-二甲基咪唑六氟磷酸盐
[Bz‥Im]X
含芳基咪唑型
[BzMIm]X
[BzMIm]Cl
36443-80-8
1-苄基-3-甲基咪唑氯盐
1-Benzyl-3-MethylImidazoliumChloride
[BzMIm]Br
65039-11-4
1-苄基-3-甲基咪唑溴盐
1-Benzyl-3-MethylImidazolium
[BzMIm]BF4
500996-04-3
1-苄基-3-甲基咪唑四氟硼酸盐
1-Benzyl-3-MethylImidazolium
[BzMIm]PF6
433337-11-2
1-苄基-3-甲基咪唑六氟磷酸盐
1-Benzyl-3-MethylImidazolium
[BzMIm]SbF4
1-苄基-3-甲基咪唑六氟锑酸盐
1-Benzyl-3-MethylImidazolium
[BzMIm]HSO4
956597-95-8
1-苄基-3-甲基咪唑硫酸氢盐
1-Benzyl-3-MethylImidazolium
[BzMIm]SOM
1005735-56-7
1-苄基-3-甲基咪唑硫酸甲酯盐
1-Benzyl-3-MethylImidazolium
[BzMIm]MS
936014-36-7
1-苄基-3-甲基咪唑甲磺酸盐
1-Benzyl-3-MethylImidazolium
[BzMIm]TS
52461-83-3
1-苄基-3-甲基咪唑对甲苯磺酸盐
1-Benzyl-3-MethylImidazolium
[BzMIm]TfS
606925-13-7
1-苄基-3-甲基咪唑三氟甲磺酸盐
1-Benzyl-3-MethylImidazolium
[BzMIm]NTf2
433337-24-7
1-苄基-3-甲基咪唑双三氟甲磺酰亚胺盐
1-Benzyl-3-MethylImidazolium
[BzMIm]NO3
1-苄基-3-甲基咪唑硝酸盐
1-Benzyl-3-MethylImidazolium
[BzMIm]DCA
1-苄基-3-甲基咪唑二氰胺盐
1-Benzyl-3-MethylImidazolium
[BzM2Im]X
[BzM2Im]Cl
36443-79-5
1-苄基-2,3-二甲基咪唑氯盐
1-Benzyl-2,3-diMethylImidazolium
[BzM2Im]Br
862999-80-2
1-苄基-2,3-二甲基咪唑溴盐
1-Benzyl-2,3-diMethylImidazolium
[BzM2Im]BF4
862999-75-5
1-苄基-2,3-二甲基咪唑四氟硼酸盐
1-Benzyl-2,3-diMethylImidazolium
[BzM2Im]PF6
1-苄基-2,3-二甲基咪唑六氟磷酸盐
1-Benzyl-2,3-diMethylImidazolium
[BzM2Im]SbF6
1-苄基-2,3-二甲基咪唑六氟锑酸盐
1-Benzyl-2,3-diMethylImidazolium
[BzM2Im]TfS
1-苄基-2,3-二甲基咪唑三氟甲磺酸盐
1-Benzyl-2,3-diMethylImidazolium
[BzM2Im]NTf2
213011-04-2
1-苄基-2,3-二甲基咪唑双三氟甲磺酰亚胺盐
1-Benzyl-2,3-diMethylImidazolium
[C12MBzMIm]X
[C12M(BzM)Im]Cl
21054-72-8
1-十二烷基-2-甲基-3-苯甲基咪唑氯盐
1-Dodecyl-2-Methyl-3-BenzylImidazoliumChloride
[V‥Im]X
含烯烃基咪唑型
[VMIm]X
[VMIm]Cl
1-乙烯基-3-甲基咪唑氯盐
1-Vinyl-3-MethylImidazoliumChloride
[VMIm]Br
1-乙烯基-3-甲基咪唑溴盐
1-Vinyl-3-MethylImidazoliumBromide
[VMIm]I
29322-86-9
1-乙烯基-3-甲基咪唑碘盐
1-Vinyl-3-MethylImidazoliumIodide
[VMIm]BF4
911289-19-5
1-乙烯基-3-甲基咪唑四氟硼酸盐
1-Vinyl-3-MethylImidazoliumtetraFluoroBorate
[VMIm]PF6
1-乙烯基-3-甲基咪唑六氟磷酸盐
1-Vinyl-3-MethylImidazoliumhexaFluoroPhosphate
[VMIm]SbF6
1-乙烯基-3-甲基咪唑六氟锑酸盐
1-Vinyl-3-MethylImidazoliumhexaFluoroAntimonate
[VMIm]SOM
26591-72-0
1-乙烯基-3-甲基咪唑硫酸甲酯盐
1-Vinyl-3-MethylImidazoliumMethylSulfate
[VMIm]POM2
1-乙烯基-3-甲基咪唑磷酸二甲酯盐
1-Vinyl-3-MethylImidazoliumdiMethylPhosphate
[VMIm]MS
264255-37-0
1-乙烯基-3-甲基咪唑甲磺酸盐
1-Vinyl-3-MethylImidazoliumMethaneSulfonate
[VMIm]TS
187387-86-6
1-乙烯基-3-甲基咪唑对甲苯磺酸盐
1-Vinyl-3-MethylImidazoliumTosylate
[VMIm]TfS
187387-89-9
1-乙烯基-3-甲基咪唑三氟甲磺酸盐
1-Vinyl-3-MethylImidazoliumtriFluoroMethaneSulfonate
[VMIm]NTf2
1-乙烯基-3-甲基咪唑双三氟甲磺酰亚胺盐
1-Vinyl-3-MethylImidazoliumbis(triFluoroMethylSulfonyl)Imide
[VMIm]NO3
1072788-90-9
1-乙烯基-3-甲基咪唑硝酸盐
1-Vinyl-3-MethylImidazoliumNitrate
[VMIm]ClO4
1-乙烯基-3-甲基咪唑高氯酸盐
1-Vinyl-3-MethylImidazoliumperChloride
[VMIm]DCA
1-乙烯基-3-甲基咪唑二氰胺盐
1-Vinyl-3-MethylImidazoliumdiCyanAmide
[VMIm]Ac
1-乙烯基-3-甲基咪唑醋酸盐
1-Vinyl-3-MethylImidazoliumAcetate
[VMIm]X.xFeY3
[VMIm]Cl.FeCl3
1-乙烯基-3-甲基咪唑氯合氯化铁盐
[AMIm]X
[AMIm]Cl
65039-10-3
1-烯丙基-3-甲基咪唑氯盐
1-Allyl-3-MethylImidazoliumChloride
[AMIm]Br
31410-07-8
1-烯丙基-3-甲基咪唑溴盐
1-Allyl-3-MethylImidazoliumBromide
[AMIm]I
65039-07-8
1-烯丙基-3-甲基咪唑碘盐
1-Allyl-3-MethylImidazoliumIodide
[AMIm]BF4
851606-63-8
1-烯丙基-3-甲基咪唑四氟硼酸盐
1-Allyl-3-MethylImidazoliumtetraFluoroBorate
[AMIm]PF6
861908-19-2
1-烯丙基-3-甲基咪唑六氟磷酸盐
1-Allyl-3-MethylImidazoliumhexaFluoroPhosphate
[AMIm]TS
1-烯丙基-3-甲基咪唑对甲苯磺酸盐
1-Allyl-3-MethylImidazoliumTosylate
[AMIm]NTf2
655249-87-9
1-烯丙基-3-甲基咪唑双三氟甲磺酰亚胺盐
1-Allyl-3-MethylImidazoliumbis(triFluoroMethylSulfonyl)Imide
[AMIm]NO3
1-烯丙基-3-甲基咪唑硝酸盐
1-Allyl-3-MethylImidazoliumNitrate
[AMIm]ClO4
1-烯丙基-3-甲基咪唑高氯酸盐
1-Allyl-3-MethylImidazoliumperChloride
[AMIm]DCA
917956-73-1
1-烯丙基-3-甲基咪唑二氰胺盐
1-Allyl-3-MethylImidazoliumdiCyanAmide
[AMIm]Ac
1-烯丙基-3-甲基咪唑醋酸盐
1-Allyl-3-MethylImidazoliumAcetate
[VEIm]X
[VEIm]Br
81517-60-4
1-乙烯基-3-乙基咪唑溴盐
1-Vinyl-3-EthylImidazoliumBromide
[VEIm]I
131566-27-3
1-乙烯基-3-乙基咪唑碘盐
1-Vinyl-3-EthylImidazoliumIodide
[VEIm]BF4
936030-51-2
1-乙烯基-3-乙基咪唑四氟硼酸盐
1-Vinyl-3-EthylImidazoliumtetraFluoroBorate
[VEIm]PF6
1034364-43-6
1-乙烯基-3-乙基咪唑六氟磷酸盐
1-Vinyl-3-EthylImidazoliumhexaFluoroPhosphate
[VEIm]SbF6
1-乙烯基-3-乙基咪唑六氟锑酸盐
1-Vinyl-3-EthylImidazoliumhexaFluoroAntimonate
[VEIm]HSO4
1-乙烯基-3-乙基咪唑硫酸氢盐
1-Vinyl-3-EthylImidazoliumHydrogenSulfate
[VEIm]SOE
1-乙烯基-3-乙基咪唑硫酸乙酯盐
1-Vinyl-3-EthylImidazoliumEthylSulfate
[VEIm]POE2
1-乙烯基-3-乙基咪唑磷酸二乙酯盐
1-Vinyl-3-EthylImidazoliumdiEthylPhosphate
[VEIm]MS
1-乙烯基-3-乙基咪唑甲磺酸盐
1-Vinyl-3-EthylImidazoliumMethaneSulfonate
[VEIm]TS
321842-74-4
1-乙烯基-3-乙基咪唑对甲苯磺酸盐
1-Vinyl-3-EthylImidazoliumTosylate
[VEIm]TfS
932031-93-1
1-乙烯基-3-乙基咪唑三氟甲磺酸盐
1-Vinyl-3-EthylImidazoliumtriFluoroMethaneSulfonate
[VEIm]NTf2
204854-22-8
1-乙烯基-3-乙基咪唑双三氟甲磺酰亚胺盐
1-Vinyl-3-EthylImidazoliumbis(triFluoroMethylSulfonyl)Imide
[VEIm]NO3
1-乙烯基-3-乙基咪唑硝酸盐
1-Vinyl-3-EthylImidazoliumNitrate
[VEIm]ClO4
1-乙烯基-3-乙基咪唑高氯酸盐
1-Vinyl-3-EthylImidazoliumperChloride
[VEIm]DCA
1-乙烯基-3-乙基咪唑二氰胺盐
1-Vinyl-3-EthylImidazoliumdiCyanAmide
[VEIm]Ac
1109210-45-8
1-乙烯基-3-乙基咪唑醋酸盐
1-Vinyl-3-EthylImidazoliumAcetate
[VEIm]TfA
1-乙烯基-3-乙基咪唑三氟乙酸盐
1-Vinyl-3-EthylImidazoliumtriFluoroAcetate
[AEIm]X
[AEIm]Cl
1-烯丙基-3-乙基咪唑氯盐
1-Allyl-3-EthylImidazoliumChloride
[AEIm]Br
1-烯丙基-3-乙基咪唑溴盐
1-Allyl-3-EthylImidazoliumBromide
[AEIm]BF4
1-烯丙基-3-乙基咪唑四氟硼酸盐
1-Allyl-3-EthylImidazoliumtetraFluoroBorate
[AEIm]PF6
1-烯丙基-3-乙基咪唑六氟磷酸盐
1-Allyl-3-EthylImidazolium
[AEIm]NTf2
1-烯丙基-3-乙基咪唑双三氟甲磺酰亚胺盐
1-Allyl-3-EthylImidazolium
[AEIm]NO3
1-烯丙基-3-乙基咪唑硝酸盐
1-Allyl-3-EthylImidazolium
[AEIm]DCA
1-烯丙基-3-乙基咪唑二氰胺盐
1-Allyl-3-EthylImidazolium
[VPIm]X
[VPIm]Cl
1-乙烯基-3-丙基咪唑溴盐
1-Vinyl-3-PropylImidazoliumChloride
[VPIm]I
1-乙烯基-3-丙基咪唑碘盐
1-Vinyl-3-PropylImidazolium
[VPIm]PF6
1-乙烯基-3-丙基咪唑六氟磷酸盐
1-Vinyl-3-PropylImidazolium
[VPIm]SbF6
1-乙烯基-3-丙基咪唑六氟锑酸盐
1-Vinyl-3-PropylImidazolium
[VPIm]MS
1-乙烯基-3-丙基咪唑甲磺酸盐
1-Vinyl-3-PropylImidazolium
[VPIm]TS
1-乙烯基-3-丙基咪唑对甲苯磺酸盐
1-Vinyl-3-PropylImidazolium
[VPIm]TfS
1-乙烯基-3-丙基咪唑三氟甲磺酸盐
1-Vinyl-3-PropylImidazolium
[VPIm]NTf2
1-乙烯基-3-丙基咪唑双三氟甲磺酰亚胺盐
1-Vinyl-3-PropylImidazolium
[VPIm]NO3
1-乙烯基-3-丙基咪唑硝酸盐
1-Vinyl-3-PropylImidazolium
[VPIm]ClO4
1-乙烯基-3-丙基咪唑高氯酸盐
1-Vinyl-3-PropylImidazolium
[VPIm]SCN
1-乙烯基-3-丙基咪唑硫氰酸盐
1-Vinyl-3-PropylImidazolium
[VPIm]Ac
1-乙烯基-3-丙基咪唑醋酸盐
1-Vinyl-3-PropylImidazolium
[VPIm]TfA
1-乙烯基-3-丙基咪唑三氟乙酸盐
1-Vinyl-3-PropylImidazolium
[VBIm]X
[VBIm]Cl
657394-65-5
1-乙烯基-3-丁基咪唑氯盐
1-Vinyl-3-ButylImidazoliumChloride
[VBIm]Br
1033461-45-8
1-乙烯基-3-丁基咪唑溴盐
1-Vinyl-3-ButylImidazoliumBromide
[VBIm]BF4
1033461-44-7
1-乙烯基-3-丁基咪唑四氟硼酸盐
1-Vinyl-3-ButylImidazoliumtetraFluoroBorate
[VBIm]PF6
915358-85-9
1-乙烯基-3-丁基咪唑六氟磷酸盐
1-Vinyl-3-ButylImidazolium
[VBIm]SbF6
1-乙烯基-3-丁基咪唑六氟锑酸盐
1-Vinyl-3-ButylImidazolium
[VBIm]HSO4
1-乙烯基-3-丁基咪唑硫酸氢盐
1-Vinyl-3-ButylImidazolium
[VBIm]POB2
1-乙烯基-3-丁基咪唑磷酸二丁酯盐
1-Vinyl-3-ButylImidazolium
[VBIm]MS
1-乙烯基-3-丁基咪唑甲磺酸盐
1-Vinyl-3-ButylImidazolium
[VBIm]TS
1-乙烯基-3-丁基咪唑对甲苯磺酸盐
1-Vinyl-3-ButylImidazolium
[VBIm]TfS
1-乙烯基-3-丁基咪唑三氟甲磺酸盐
1-Vinyl-3-ButylImidazolium
[VBIm]NTf2
1007390-44-4
1-乙烯基-3-丁基咪唑双三氟甲磺酰亚胺盐
1-Vinyl-3-ButylImidazolium
[VBIm]NO3
1-乙烯基-3-丁基咪唑硝酸盐
1-Vinyl-3-ButylImidazolium
[VBIm]ClO4
1-乙烯基-3-丁基咪唑高氯酸盐
1-Vinyl-3-ButylImidazolium
[VBIm]SCN
1-乙烯基-3-丁基咪唑硫氰酸盐
1-Vinyl-3-ButylImidazolium
[VBIm]DCA
1-乙烯基-3-丁基咪唑二氰胺盐
1-Vinyl-3-ButylImidazolium
[ABIm]X
[ABIm]Cl
1-烯丙基-3-丁基咪唑氯盐
1-Allyl-3-ButylImidazoliumChloride
[ABIm]Br
1-烯丙基-3-丁基咪唑溴盐
1-Allyl-3-ButylImidazoliumBromide
[ABIm]BF4
1-烯丙基-3-丁基咪唑四氟硼酸盐
1-Allyl-3-ButylImidazoliumtetraFluoroBorate
[ABIm]PF6
1-烯丙基-3-丁基咪唑六氟磷酸盐
1-Allyl-3-ButylImidazolium
[ABIm]NTf2
1-烯丙基-3-丁基咪唑双三氟甲磺酰亚胺盐
1-Allyl-3-ButylImidazolium
[ABIm]NO3
1-烯丙基-3-丁基咪唑硝酸盐
1-Allyl-3ButylImidazolium
[ABIm]DCA
1-烯丙基-3-丁基咪唑二氰胺盐
1-Allyl-3-ButylImidazolium
[VHIm]X
[VHIm]Br
1-Vinyl-3-HexylImidazolium
[VHIm]BF4
1-Vinyl-3-HexylImidazoliumtetraFluoroBorate
[VHIm]PF6
1-Vinyl-3-HexylImidazolium
[AHIm]X
[AHIm]Cl
1-烯丙基-3-己基咪唑氯盐
1-Allyl-3-HexylImidazoliumChloride
[AHIm]Br
1-烯丙基-3-己基咪唑溴盐
1-Allyl-3-HexylImidazoliumBromide
[AHIm]BF4
1-烯丙基-3-己基咪唑四氟硼酸盐
1-Allyl-3-HexylImidazolium
[AHIm]NTf2
1-烯丙基-3-己基咪唑双三氟甲磺酰亚胺盐
1-Allyl-3-HexylImidazolium
[AHIm]NO3
1-烯丙基-3-己基咪唑硝酸盐
1-Allyl-3-HexylImidazolium
[VOIm]X
[VOIm]PF6
1-Vinyl-3-OctylImidazolium
[AOIm]X
[AOIm]Cl
1-烯丙基-3-辛基咪唑氯盐
1-Allyl-3-OctylImidazoliumChloride
[AOIm]Br
1-烯丙基-3-辛基咪唑溴盐
1-Allyl-3-OctylImidazoliumBromide
[AOIm]BF4
1-烯丙基-3-辛基咪唑四氟硼酸盐
1-Allyl-3-OctylImidazoliumtetraFluoroBorate
[AOIm]PF6
1-烯丙基-3-辛基咪唑六氟磷酸盐
1-Allyl-3-OctylImidazolium
[AOIm]NTf2
1-烯丙基-3-辛基咪唑双三氟甲磺酰亚胺盐
1-Allyl-3-OctylImidazolium
[AOIm]NO3
1-烯丙基-3-辛基咪唑硝酸盐
1-Allyl-3-OctylImidazolium
[VBzIm]X
[VBzIm]Cl
79637-05-1
1-乙烯基-3-苄基咪唑氯盐
1-Vinyl-3-BenzylImidazoliumChloride
[VBzIm]Br
67691-05-8
1-乙烯基-3-苄基咪唑溴盐
1-Vinyl-3-BenzylImidazoliumBromide
[VBzIm]BF4
1-乙烯基-3-苄基咪唑四氟硼酸盐
1-Vinyl-3-BenzylImidazoliumtetraFluoroBorate
[VBzIm]PF6
1-乙烯基-3-苄基咪唑六氟磷酸盐
1-Vinyl-3-BenzylImidazolium
[VBzIm]SbF6
1-乙烯基-3-苄基咪唑六氟锑酸盐
1-Vinyl-3-BenzylImidazolium
[VBzIm]HSO4
1-乙烯基-3-苄基咪唑硫酸氢盐
1-Vinyl-3-BenzylImidazolium
[VBzIm]MS
1-乙烯基-3-苄基咪唑甲磺酸盐
1-Vinyl-3-BenzylImidazolium
[VBzIm]TfS
1-乙烯基-3-苄基咪唑三氟甲磺酸盐
1-Vinyl-3-BenzylImidazolium
[VBzIm]NTf2
1-乙烯基-3-苄基咪唑双三氟甲磺酰亚胺盐
1-Vinyl-3-BenzylImidazolium
[VBzIm]NO3
1-乙烯基-3-苄基咪唑硝酸盐
1-Vinyl-3-BenzylImidazolium
[VBzIm]SCN
1-乙烯基-3-苄基咪唑硫氰酸盐
1-Vinyl-3-BenzylImidazolium
[VBzIm]DCA
1-乙烯基-3-苄基咪唑二氰胺盐
1-Vinyl-3-BenzylImidazolium
[AVIm]X
[AVIm]Cl
100894-64-2
1-烯丙基-3-乙烯基咪唑氯盐
1-Allyl-3-VinylImidazoliumChloride
[AVIm]Br
1072788-73-8
1-烯丙基-3-乙烯基咪唑溴盐
1-Allyl-3-VinylImidazoliumBromide
[AVIm]I
1-烯丙基-3-乙烯基咪唑碘盐
1-Allyl-3-VinylImidazolium
[AVIm]BF4
936030-54-5
1-烯丙基-3-乙烯基咪唑四氟硼酸盐
1-Allyl-3-VinylImidazoliumtetraFluoroBorate
[AVIm]PF6
1-烯丙基-3-乙烯基咪唑六氟磷酸盐
1-Allyl-3-VinylImidazolium
[AVIm]NTf2
1-烯丙基-3-乙烯基咪唑双三氟甲磺酰亚胺盐
1-Allyl-3-VinylImidazolium
[AVIm]NO3
1-烯丙基-3-乙烯基咪唑硝酸盐
1-Allyl-3-VinylImidazolium
[AVIm]DCA
1-烯丙基-3-乙烯基咪唑二氰胺盐
1-Allyl-3-VinylImidazolium
[VM2Im]X
[AM2Im]Cl
1-烯丙基-2,3-二甲基咪唑氯盐
1-Allyl-3-diMethylImidazoliumChloride
[AM2Im]Br
693226-62-9
1-烯丙基-2,3-二甲基咪唑溴盐
1-Allyl-3-diMethylImidazoliumBromide
[AM2Im]I
111732-86-6
1-烯丙基-2,3-二甲基咪唑碘盐
1-Allyl-3-diMethylImidazolium
[AM2Im]BF4
640282-12-8
1-烯丙基-2,3-二甲基咪唑四氟硼酸盐
1-Allyl-3-diMethylImidazoliumtetraFluoroBorate
[AM2Im]PF6
1-烯丙基-2,3-二甲基咪唑六氟磷酸盐
1-Allyl-3-diMethylImidazolium
[AM2Im]SbF6
1-烯丙基-2,3-二甲基咪唑六氟锑酸盐
1-Allyl-3-diMethylImidazolium
[AM2Im]NTf2
1005757-37-8
1-烯丙基-2,3-二甲基咪唑双三氟甲磺酰亚胺盐
1-Allyl-3-diMethylImidazolium
[V2EIm]X
[A2EIm]Cl
1,3-二烯丙基-2-乙基咪唑氯盐
1,3-diAllyl-2-EthylImidazolium
[HO‥Im]X
含羟基咪唑型
[(HOC2)MIm]X
[(HOC2)MIm]Cl
61755-34-8
1-羟乙基-3-甲基咪唑氯盐
1-HydroxylEthyl-3-MethylImidazoliumChloride
[(HOC2)MIm]Br
1-HydroxylEthyl-3-MethylImidazoliumBromide
[(HOC2)MIm]BF4
374564-83-7
1-羟乙基-3-甲基咪唑四氟硼酸盐
1-HydroxylEthyl-3-MethylImidazoliumtetraFluoroBorate
[(HOC2)MIm]PF6
1-羟乙基-3-甲基咪唑六氟磷酸盐
1-HydroxylEthyl-3-MethylImidazoliumhexaFluoroPhosphate
[(HOC2)MIm]HSO4
1-羟乙基-3-甲基咪唑硫酸氢盐
1-HydroxylEthyl-3-MethylImidazoliumHydrogenSulfate
[(HOC2)MIm]TS
1-羟乙基-3-甲基咪唑对甲苯磺酸盐
1-HydroxylEthyl-3-MethylImidazoliumTosylate
[(HOC2)MIm]TfS
1-羟乙基-3-甲基咪唑三氟甲磺酸盐
[(HOC2)MIm]NTf2
174899-86-6
1-羟乙基-3-甲基咪唑双三氟甲磺酰亚胺盐
1-HydroxylEthyl-3-MethylImidazoliumbis(triFluoroMethylSulfonyl)Imide
[IHOC2)MIm]NO3
1-羟乙基-3-甲基咪唑硝酸盐
1-HydroxylEthyl-3-MethylImidazoliumNitrate
[(HOC2)MIm]ClO4
1-羟乙基-3-甲基咪唑高氯酸盐
1-HydroxylEthyl-3-MethylImidazoliumperChlorate
[(HOC2)MIm]DCA
1-羟乙基-3-甲基咪唑二氰胺盐
1-HydroxylEthyl-3-MethylImidazoliumdiCyanAmide
[(HOC2)M2Im]X
[(HOC2)M2Im]Cl
1-羟乙基-2,3-二甲基咪唑氯盐
1-HydroxylEthyl-2,3-diMethylImidazoliumChloride
[(HOC2)M2Im]BF4
1-羟乙基-2,3-二甲基咪唑四氟硼酸盐
1-HydroxylEthyl-2,3-diMethylImidazoliumtetraFluoroBorate
[(HOC2)M2Im]PF6
1-羟乙基-2,3-二甲基咪唑六氟磷酸盐
1-HydroxylEthyl-2,3-diMethylImidazoliumhexaFluoroPhosphate
[(HOC2)M2Im]HSO4
1-羟乙基-2,3-二甲基咪唑硫酸氢盐
1-HydroxylEthyl-2,3-diMethylImidazoliumHydrogenSulfate
[(HOC2)M2Im]TS
1-羟乙基-2,3-二甲基咪唑对甲苯磺酸盐
1-HydroxylEthyl-2,3-diMethylImidazoliumTosylate
[(HOC2)M2Im]NTf2
1-羟乙基-2,3-二甲基咪唑双三氟甲磺酰亚胺盐
1-HydroxylEthyl-2,3-diMethylImidazoliumbis(triFluoroMethylSulfonyl)Imide
[(HOC2)M2Im]NO3
1-羟乙基-2,3-二甲基咪唑硝酸盐
1-HydroxylEthyl-2,3-diMethylImidazoliumNitrate
[(HOC2)M2Im]ClO4
1-羟乙基-2,3-二甲基咪唑高氯酸盐
1-HydroxylEthyl-2,3-diMethylImidazoliumperChlorate
[(HOC2)M2Im]DCA
1-羟乙基-2,3-二甲基咪唑二氰胺盐
1-HydroxylEthyl-2,3-diMethylImidazoliumdiCyanAmide
[O3S‥Im]X
含磺酸基咪唑型
[(O3SC3)MIm]X
[(O3SC3)MIm]
1-磺酸丙基-3-甲基咪唑内盐
1-PropylSulfonic-3-MethylImidazolium
[(O3SC3)MIm]Cl
1-磺酸丙基-3-甲基咪唑氯盐
1-PropylSulfonic-3-MethylImidazoliumChloride
[(O3SC3)MIm]BF4
1-磺酸丙基-3-甲基咪唑四氟硼酸盐
1-PropylSulfonic-3-MethylImidazoliumtetraFluoroBorate
[(O3SC3)MIm]HSO4
[(O3SC3)MIm]H2PO4
1-磺酸丙基-3-甲基咪唑磷酸二氢盐
1-PropylSulfonic-3-MethylImidazoliumdiHydrogenPhosphate
[(O3SC3)MIm]TfS
1-磺酸丙基-3-甲基咪唑三氟甲磺酸盐
1-PropylSulfonic-3-MethylImidazoliumtriFluoroMethaneSulfonate
[(O3SC3)MIm]TfAc
1-磺酸丙基-3-甲基咪唑三氟乙酸盐
1-PropylSulfonic-3-MethylImidazoliumtriFluoroAcetate
[(O3SC4)MIm]X
{(O3SC4)MIm}
179863-07-1
1-磺酸丁基-3-甲基咪唑内盐
1-PropylSulfonic-3-MethylImidazolium
[(O3SC4)MIm]Cl
1-磺酸丁基-3-甲基咪唑氯盐
1-PropylSulfonic-3-MethylImidazoliumChloride
[(O3SC4)MIm]BF4
1-磺酸丁基-3-甲基咪唑四氟硼酸盐
1-PropylSulfonic-3-MethylImidazoliumtetraFluoroBorate
[(O3SC4)MIm]HSO4
1-磺酸丁基-3-甲基咪唑硫酸氢盐
1-PropylSulfonic-3-MethylImidazoliumHydrogenSulfate
[(O3SC4)MIm]H2PO4
1-磺酸丁基-3-甲基咪唑磷酸二氢盐
1-PropylSulfonic-3-MethylImidazoliumdiHydrogenPhosphate
[(O3SC4)MIm]TfS
1-磺酸丁基-3-甲基咪唑三氟甲磺酸盐
1-PropylSulfonic-3-MethylImidazoliumtriFluoroMethaneSulfonate
[(O3SC4)MIm]TfAc
1-磺酸丁基-3-甲基咪唑三氟乙酸盐
1-PropylSulfonic-3-MethylImidazoliumtriFluoroAcetate
[H2N‥Im]X
含氨基咪唑型
[(H2NC2)MIm]X
[(H2NC2)MIm]Br
1-胺乙基-3-甲基咪唑溴盐
1-AminoEthyl-3-MethylImidazoliumBromide
[(H2NC2)MIm]BF4
1-胺乙基-3-甲基咪唑四氟硼酸盐
1-AminoEthyl-3-MethylImidazoliumtetraFluoroBorate
[(H2NC2)MIm]PF6
1-胺乙基-3-甲基咪唑六氟磷酸盐
1-AminoEthyl-3-MethylImidazoliumhexaFluoroPhosphate
[(H2NC2)MIm]NTf2
1-胺乙基-3-甲基咪唑双三氟甲磺酰亚胺盐
1-AminoEthyl-3-MethylImidazoliumbis(triFluoroMethylSulfonyl)Imide
[(H2NC2)MIm]NO3
1-胺乙基-3-甲基咪唑硝酸盐
1-AminoEthyl-3-MethylImidazoliumNitrate
[(H2NC3)MIm]X
[(H2NC3)MIm]Cl
1-胺丙基-3-甲基咪唑氯盐
1-AminoPropyl-3-MethylImidazoliumChloride
[(H2NC3)MIm]Br
1-胺丙基-3-甲基咪唑溴盐
1-AminoPropyl-3-MethylImidazoliumBromide
[(H2NC3)MIm]BF4
1-胺丙基-3-甲基咪唑四氟硼酸盐
1-AminoPropyl-3-MethylImidazoliumtetraFluoroBorate
[(H2NC3)MIm]PF6
1-胺丙基-3-甲基咪唑六氟磷酸盐
1-AminoPropyl-3-MethylImidazoliumhexaFluoroPhosphat
[(H2NC3)MIm]NTf2
1-胺丙基-3-甲基咪唑双三氟甲磺酰亚胺盐
1-AminoPropyl-3-MethylImidazoliumbis(triFluoroMethylSulfonyl)Imide
[(H2NC3)MIm]NO3
1-胺丙基-3-甲基咪唑硝酸盐
1-AminoPropyl-3-MethylImidazoliumNitrate
[(H2NC3)BIm]X
[(H2NC3)BIm]Br
1-胺丙基-3-丁基咪唑溴盐
1-AminoPropyl-3-ButylImidazoliumBromide
[(H2NC3)BIm]BF4
1-胺丙基-3-丁基咪唑四氟硼酸盐
1-AminoPropyl-3-ButylImidazoliumtetraFluoroBorate
[(H2NC3)BIm]PF6
1-胺丙基-3-丁基咪唑六氟磷酸盐
1-AminoPropyl-3-ButylImidazoliumhexaFluoroPhosphate
[HOO‥Im]X
含羧基咪唑型
[(HOOC1)MIm]X
[(HOOC1)MIm]Cl
700370-07-6
1-羧甲基-3-甲基咪唑氯盐
1-CarboxyMethyl-3-MethylImidazoliumChloride
[(HOOC1)MIm]Br
1-羧甲基-3-甲基咪唑溴盐
1-CarboxyMethyl-3-MethylImidazoliumBromide
[(HOOC1)MIm]HSO4
1-羧甲基-3-甲基咪唑硫酸氢盐
1-CarboxyMethyl-3-MethylImidazoliumHydrogenSulfate
[(HOOC1)MIm]NTf2
671793-16-1
1-羧甲基-3-甲基咪唑双三氟甲磺酰亚胺盐
1-CarboxyMethyl-3-MethylImidazoliumbis(triFluoroMethylSulfonyl)Imide
[(HOOC1)MIm]NO3
1-羧甲基-3-甲基咪唑硝酸盐
1-CarboxyMethyl-3-MethylImidazoliumNitrate
[(HOOC2)MIm]X
[(HOOC2)MIm]Cl
1-羧乙基-3-甲基咪唑氯盐
1-CarboxyEthyl-3-MethylImidazoliumChloride
[(HOOC2)MIm]NTf2
1-羧乙基-3-甲基咪唑双三氟甲磺酰亚胺盐
1-CarboxyEthyl-3-MethylImidazoliumbis(triFluoroMethylSulfonyl)Imide
[O.Im]X
含醚键咪唑型
[(EOM)MIm]X
[(EOM)MIm]Br
1-乙氧基甲基-3-甲基咪唑溴盐
1-EthoxyMethyl-3-MethylImidazoliumBromide
[(EOM)MIm]BF4
1-乙氧基甲基-3-甲基咪唑四氟硼酸盐
1-EthoxyMethyl-3-MethylImidazoliumtetraFluoroBorate
[(EOM)MIm]PF6
1-乙氧基甲基-3-甲基咪唑六氟磷酸盐
1-EthoxyMethyl-3-MethylImidazoliumhexaFluoroPhosphate
[(EOM)MIm]NTf2
1-乙氧基甲基-3-甲基咪唑双三氟甲磺酰亚胺盐
1-EthoxyMethyl-3-MethylImidazoliumbis(triFluoroMethylSulfonyl)Imide
[(EOM)MIm]NO3
1-乙氧基甲基-3-甲基咪唑硝酸盐
1-EthoxyMethyl-3-MethylImidazoliumNitrate
[(EOM)MIm]DCA
1-乙氧基甲基-3-甲基咪唑二氰胺盐
1-EthoxyMethyl-3-MethylImidazoliumdiCyanAmide
[(EOE)MIm]X
[(EOE)MIm]Br
1-乙氧基乙基-3-甲基咪唑溴盐
1-EthoxyEthyl-3-MethylImidazoliumBromide
[(EOE)MIm]BF4
1-乙氧基乙基-3-甲基咪唑四氟硼酸盐
1-EthoxyEthyl-3-MethylImidazoliumtetraFluoroBorate
[(EOE)MIm]PF6
1-乙氧基乙基-3-甲基咪唑六氟磷酸盐
1-EthoxyEthyl-3-MethylImidazoliumhexaFluoroPhosphate
[(EOE)MIm]NTf2
1-乙氧基乙基-3-甲基咪唑双三氟甲磺酰亚胺盐
1-EthoxyEthyl-3-MethylImidazoliumbis(triFluoroMethylSulfonyl)Imide
[(EOE)MIm]NO3
1-乙氧基乙基-3-甲基咪唑硝酸盐
1-EthoxyEthyl-3-MethylImidazoliumNitrate
[(EOE)MIm]DCA
1-乙氧基乙基-3-甲基咪唑二氰胺盐
1-EthoxyEthyl-3-MethylImidazoliumdiCyanAmide
[.OO.Im]X
脂基咪唑型
[(EOOE)MIm]Cl
1-乙酸乙酯基-3-甲基咪唑氯盐
1-AcetoxyEthyl-3-MethylImidazoliumChloride
[(EOOE)MIm]BF4
1-乙酸乙酯基-3-甲基咪唑四氟硼酸盐
1-AcetoxyEthyl-3-MethylImidazoliumtetraFluoroBorate
[(EOOE)MIm]PF6
1-乙酸乙酯基-3-甲基咪唑六氟磷酸盐
1-AcetoxyEthyl-3-MethylImidazoliumhexaFluoroPhosphate
[(EOOE)MIm]NTf2
1-乙酸乙酯基-3-甲基咪唑双三氟甲磺酰亚胺盐
1-AcetoxyEthyl-3-MethylImidazoliumbis(triFluoroMethylSulfonyl)Imide
[XXIm]X
荧光咪唑型
1-芴基-3-甲基咪唑溴盐
1-芴基-3-甲基咪唑四氟硼酸盐
1-芴基-3-甲基咪唑六氟磷酸盐
1-芴基-3-甲基咪唑双三氟甲磺酰亚胺盐
2-1,3-二芴基咪唑溴盐
1,3-二芴基咪唑四氟硼酸盐
1,3-二芴基咪唑六氟磷酸盐
1,3-二芴基咪唑双三氟甲磺酰亚胺盐
[(P..)Im]P..
聚合咪唑型
[(PVBz)MIm]PF6
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小编:wyf 11.03